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Water has a simple molecular structure. It is composed of one oxygen atom and two hydrogen atoms. Each hydrogen atom is covalently bonded to the oxygen via a shared pair of electrons.
Structure of water
Structure of water
A covalent chemical bond consists of a pair of electrons shared between two atoms. In the water molecule H2O, the single electron of each H is shared with one of the six outer-shell electrons of the oxygen, leaving four electrons, which are organized into two non-bonding pairs. Thus the oxygen atom is surrounded by four electron pairs that would ordinarily tend to arrange themselves as far from each other as possible in order to minimize repulsions between these clouds of negative charge. This would ordinarily result in a tetrahedral geometry in which the angle between electron pairs (and therefore the H-O-H bond angle) is 109°. However, because the two non-bonding pairs remain closer to the oxygen atom, these exert a stronger repulsion against the two covalent bonding pairs, effectively pushing the two hydrogen atoms closer together. The result is a distorted tetrahedral arrangement in which the H—O—H angle is 104.5°. The O-H bond lengths are 0.096 nm.
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